Abstract
The subject of a doctoral dissertation was evaluation of quantitative effects of enzymatic treatment and a wide chemical surface modification of polyester fibres varying in physical initial micro-structure and the consequences in terms of surface properties and selected volume properties of investigated fibres.
Glossy, continuous polyester fibres with poly(ethylene terephthalate) with different draw ratios (R = 3,0x; R = 3,5x; R = 4,0x; R = 5,2x) were used for the investigations.
The modification of PET fibre by the chemical method was carried out with the use of sodium hydroxide solutions and amine solutions with different functionality and by the biochemical method using the enzymatic preparations diversified with respect to their origin, biochemical characteristics and application conditions. Effect of enzymatic modification, at proper selection of enzyme, it is more advantageous from gotten in classic chemical modification at utilization of solution NaOH, as well as amines one and two-function and it is subordinated from kind of enzymatic preparations.
In the light of the test results obtained the method of PET fibres modification with the use of enzymatic preparations should be accepted as an effective, proecological and energy-saving approach to changing the fibre surface structure leading to the elimination or essential reduction of several unfavourable fibre properties.
References
Sanders E.M., Zeronian S.H.: J. Appl. Polym. Sci., 1982, 27, 4477.
Ellison Ellison M.S., Fisher L.D. i in.: J. Appl. Polym. Sci., 1982, 27, 247.
Dave J., Kumar R., Srivastava H.C.: J. Appl. Polym. Sci., 1987, 33, 455.
Collins M.J., Zeronian S.H.: J. Appl. Polym. Sci., 1992, 45, 797.
East G.C, Rahman M.: J. Appl. Polym. Sci., 2006, 102, 4814.
Zeronian S.H., Collins M.J. i in.: Indust. Fabr., 1984, 3, 19.
Chauhan R.S., Rao M.V., Oweltz N.E.: J. Appl. Polym. Sci., 1985, 30, 1.
Collins M.J., Zheronian S.G., Marshall M.L.: J Macromol Sci., 1991, A28, 775.
Avny Y., Rebenfeld L.: J.Appl. Polym. Sci., 1986, 32, 4009.
Awodi Y., Johnson A. i in.: J Appl Polym Sci., 1987, 33, 2503.
Haghighat Kish M., Borhani S.: J.Appl. Polym. Sci., 2000, 78, 1923.
Bendak A., El-Marsafi S.: Journal of Islamic Academy of Sciences, 1991, 4, 275.
Bide Bide M., Zhong T. i in.: AATCC Rewiev, 2003, 11, 24.
Phaneuf M.D., Deutsch E.R. i in.: AATCC Review, 2005, 5, 39.
Kardas I.: Modyfikacja powierzchni włókien poliestrowych i uwarunkowanie jej efektów parametrami budowy wyjściowej włókna, Praca doktorska, PŁ 2008.
Allen N.S., Edge M. i in.: Polym. Degrad. Stab., 1994, 43, 229.
Edge M., Hayes M. i in.: Polym. Degrad. Stab., 32, 1991, 131.
Allen N.S., Edge M., Mohammadian M., Jones K.: Eur. Polym. J., 27, 1991, 1373.
Allen N.S., Edge M., Mohammadian M., Jones K.: Polym. Degrad. Stab., 41, 1993, 191.
Zeronian S.H., Collins M.J.: Text Prog., 1989, 20, 1.
Collins M.J., Zeronian S.H., Semmelmeyer M.: J. Appl. Polym. Sci., 42, 1991, 2149.
Zeronian, S. H.; Collins, M. J. Text Progr 1989, 20, 14.
Poppola A.V.: J. Appl. Polym. Sci., 1988, 36, 1677.
Holmes S.A.: Text. Res. J., 1996, 66, 214.
Holmes S. A.: Journal of Applied Polymer Science, 1996, 61, 255.
Fukatsu K.: J Appl Polym Sci, 1992, 45, 2037.
Alisch M., Feuerhack A. i in.: Biocatalysis and Biotransformation, 2004, 22, 347.
Fischer-Colbrie G., Heumann S. i in.: Biocatalysis and Biotransformation, 2004, 22, 341.
Andersen B.K., Borch K.: US Patent Nr 5,997,584, 1999.
Müller R.J., Kleeberg I., Deckwer W.D.: J. Biotechnol., 2001, 86, 87.
Yoon, M.-Y., Kellis, J. and Poulose, A.J.: AATCC Review, 2002, 2, 33.
Xie J, Hsieh YL: ACS Symp Ser., 2003, 840, 217.
Teli M.D., Purkayastha A.: Amer. Dyest. Reporter, 1993, 82, 34.
Murray R., Davis H. A., Tucker P.: J. Appl. Polym. Sci. Symp., 1978, 33, 177.
Hinrichsen G., Iburg A. i in.: Colloid and Polymer Science, Vol. 257, 1979, 1251.
Marek J., Martinkova L.: "Enzymes open the future of new PET textile applications and processing", 3rd Int. Conference on Textile Biotechnology, Graz, June 2004.
Marek J., Martinkova L.: "Enzymatic modification of synthetic PET textiles", TEXCHEM 2003, Dvúr Králové n.L., maj 2003.
Marek J., Martinkova L.: Starters Of Environmentally Friendly Finishing Processes Of Cellulose And Synthetics, Cost 628 – Final Conference Tampere, September 2005.
Vertommen M.A.M.E., Nierstrasz V.A. i in.: J. Biotechnology, 2005, 120, 376.
Zhang J., Wang X., Gong J., Gu Z.: J. Appl. Polym. Sci., 2004, 93, 1089.
Kleeberg I., Welzel K. i in.: Biomacromolecules, 2005, 6, 262.
Cho H.H., Choi S.C., Lee Y.H.: J. Korean. Soc. Text. Eng. Chem., 1984, 21, 71.
Awodi Y., Johnson A. i in.: J Appl Polym Sci., 1987, 33, 2503.
Hsieh Y.L., Miller A., Thompson J.: Textile Res. J., 1996, 66, 1.
Sammon C., YarwoodJ. , Everall N.: Polym. Degrad. Stab., 2000, 67, 149.
Silva C.M., Carneiro F. i in.: J. Polym. Sci.: Part A: Polym. Chem., 2005, 43, 2448.
O'Neill A., Cavaco-Paulo A.: Biocatalysis i Biotransformation, 2004, 22, 353
Silva, C., Cavaco-Paulo A.: Biocatalysis and Biotransformation, 2004, 22, 357
Silva C. i in.: Journal of Biotechnology, 2007, 128, 849.
Fukatsu K.: J Appl Polym Sci, 1992, 45, 2037.
Kontkanen H., Saloheimo M. i in.: Applied Microbiology and Biotechnology
Shekhar Sharma H.S..: AATCC Review, 2005, 5, 44.
McCloskey S.G., Jump J.M.: Textile Res. J., 2005, 75, 480.
Heumann S., Eberl A. i in.: J. Biochem. Biophys., 2006, 39, 89.
Bendak A., El-Marsafi S.: Journal of Islamic Academy of Sciences, 1991, 4, 275.
Liljemark N. T., Asnes H.: Text. Res. J., 1971, 41, 732.
Dyson W., Kellis, Jr. J.T. i in.: US Patent Nr 6,933,140, 2005.
Fett W.F., Wijey C. i in.: J. Appl. Microbiol., 1999, 86, 561.